ENGINEERING CHEMISTRY – II
UNIT I ELECTROCHEMISTRY Click Here To Download
Electrochemical cells – reversible and irreversible cells – EMF – measurement of emf – Single electrode potential – Nernst equation (problem) – reference electrodes –Standard Hydrogen electrode -Calomel electrode – Ion selective electrode – glass electrode and measurement of pH – electrochemical series –
significance – potentiometer titrations (redox - Fe² + vs dichromate and precipitation – Ag+ vs CI-titrations) and conduct metric titrations (acid-base – HCI vs, NaOH) titrations,
UNIT II CORROSION AND CORROSION CONTROL Click Here To Download
Chemical corrosion – Pilling – Bedworth rule – electrochemical corrosion – different types – galvanic corrosion – differential aeration corrosion – factors influencing corrosion – corrosion control – sacrificial anode and impressed cathodic current methods – corrosion inhibitors – protective coatings – paints –
constituents and functions – metallic coatings – electroplating (Au) and electroless (Ni) plating.
UNIT III FUELS AND COMBUSTION Click Here To Download
Calorific value – classification – Coal – proximate and ultimate analysis metallurgical coke – manufacture by Otto-Hoffmann method – Petroleum processing and fractions – cracking – catalytic cracking and methods-knocking – octane number and cetane number – synthetic petrol – Fischer Tropsch and Bergius processes – Gaseous fuels- water gas, producer gas, CNG and LPG, Flue gas analysis – Orsat apparatus – theoretical air for combustion.
UNIT IV PHASE RULE AND ALLOYS Click Here To Download
Statement and explanation of terms involved – one component system – water system – condensed phase rule – construction of phase diagram by thermal analysis – simple eutectic systems (lead-silver system only) – alloys – importance, ferrous alloys – nichrome and stainless steel – heat treatment of steel, non-ferrous alloys – brass and bronze.
UNIT V ANALYTICAL TECHNIQUES Click Here To Download
Beer-Lambert’s law (problem) – UV-visible spectroscopy and IR spectroscopy – principles instrumentation (problem) (block diagram only) – estimation of iron by colorimetry – flame photometry – principle – instrumentation (block diagram only)– estimation of sodium by flame photometry – atomic absorption spectroscopy – principles – instrumentation (block diagram only) – estimation of nickel by atomic
1. P.C.Jain and Monica Jain, “Engineering Chemistry” Dhanpat Rai Pub, Co., New Delhi (2002).
2. S.S.Dara “A text book of Engineering Chemistry” S.Chand & Co.Ltd., New Delhi (2006).
1. B.Sivasankar “Engineering Chemistry” Tata McGraw-Hill Pub.Co.Ltd, New Delhi (2008).
2. B.K.Sharma “Engineering Chemistry” Krishna Prakasan Media (P) Ltd., Meerut